Pressure-induced amorphization, martensitic transformations and the memory glass effect
Starts 21 May 2004 14:30
Ends 21 May 2004 20:00
Central European Time
ICTP
Main Building Room 239
Strada Costiera, 11
I - 34151 Trieste (Italy)
A large class of materials are known to transform from a crystalline to an
amorphous structure under pressure changes at constant temperature. Among
others, typical materials are water (H2O), quartz (SiO2) and berlinite
(AlPO4).
One of the striking (though rather controversial) properties observed in
some pressure-induced amorphous materials is the so-called memory glass
effect: when the amorphous sample is decompressed, the initial crystalline
structure is recovered, conserving the original crystal orientation.
Here, a model of interacting particles in two dimensions is studied in
order to address some issues related to pressure induced amorphization and
the memory glass effect. Two limit scenarios are presented according to the
nature of the mechanical instabilities underlying the transformation: a direct
crystal-to-amorphous transformation and a martensitic transformation. In
the last case the product phase can be a poly-crystal with a very small
grain size and the material can be easily taken as an amorphous material.
The memory of this \"amorphous\" structure is a natural consequence of the
underlying martensitic transformation.